Silver bromate

Silver bromate
Names
Systematic IUPAC name
Silver(I) bromate
Other names
Argentous bromate
Identifiers
CAS Number
  • 7783-89-3 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 8053699 checkY
ECHA InfoCard 100.029.120 Edit this at Wikidata
PubChem CID
  • 9878022
CompTox Dashboard (EPA)
  • DTXSID60999042 Edit this at Wikidata
InChI
  • InChI=1S/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: XQLMNMQWVCXIKR-UHFFFAOYSA-M checkY
  • InChI=1/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: XQLMNMQWVCXIKR-REWHXWOFAZ
  • [Ag+].[O-]Br(=O)=O
Properties
Chemical formula
AgBrO3
Molar mass 235.770 g/mol
Appearance white powder
photosensitive
Density 5.206 g/cm3
Melting point 309 °C (588 °F; 582 K)
Solubility in water
0.167 g/100 mL
Solubility product (Ksp)
5.38×10−5[1]
Solubility in ammonium hydroxide soluble
Hazards
GHS labelling:
Pictograms
GHS03: Oxidizing GHS07: Exclamation mark
Danger
Hazard statements
H272, H315, H319, H335
P210, P220, P261, P264, P271, P280, P302+P352, P304+P340+P312, P305+P351+P338, P332+P313, P337+P313, P362+P364, P370+P378, P403+P233, P405, P501
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references
Chemical compound
Silver bromide GIF

Silver bromate (AgBrO3), is a toxic, light and heat-sensitive, white powder.[2]

Uses

Silver bromate can be used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.[3]

References

  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. ^ Perry, Dale L. (2011). Handbook of inorganic compounds (2nd ed.). Boca Raton: Taylor & Francis. p. 365. ISBN 978-1-4398-1461-1. OCLC 587104373.
  3. ^ Mohammadpoor-Baltork, Iraj; Nourozi, Ali Reza (1999). "Efficient and Selective Oxidative Deprotection of Tetrahydropyranyl Ethers, Ethylene Acetals and Ketals with Silver and Sodium Bromates in the Presence of Aluminum Chloride". Synthesis. 1999 (3): 487–490. doi:10.1055/s-1999-3410. S2CID 196725503.

External links

  • Silver bromate solubility
  • Chemical data
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Silver(0,I)
  • Ag2F
Silver(I)
  • AgBF4
  • AgBr
  • AgBrO3
  • AgCN
  • AgCNO
  • AgCl
  • AgClO
  • AgClO2
  • AgClO3
  • AgClO4
  • AgF
  • AgI
  • AgIO3
  • AgMnO4
  • AgNO2
  • AgNO3
  • AgN3
  • Ag3N
  • AgReO4
  • AgOCN
  • AgSCN
  • AgCF3SO3
  • AgPF6
  • Ag2CO3
  • Ag2C2
  • Ag2C2O4
  • Ag2CrO4
  • Ag2Cr2O7
  • Ag2MoO4
  • Ag2O
  • Ag2S
  • Ag2SO3
  • Ag2S2O3
  • Ag2SO4
  • AgHSO4
  • Ag2Se
  • Ag2SeO3
  • Ag2Te
  • Ag3AsO4
  • Ag3PO4
  • KAg(CN)2
  • RbAg4I5
  • Ag(NH3)2OH
  • Ag2N2O2
  • Ag2WO4
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18
    H
    36
    AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11
    H
    23
    COO
  • Silver(II)
    • AgF2
    • [Ag(C5H5N)4]S2O8
    Silver(III)
    • Ag2O3
    • AgF3
    • Ag2S3
    Silver(I,III)
    • Ag4O4
    • v
    • t
    • e
    Compounds containing the bromate group
    HBrO3 He
    Li Be B C N O F Ne
    NaBrO3 Mg Al Si P S Cl Ar
    KBrO3 Ca(BrO3)2 Sc(BrO3)3 Ti V Cr Mn(BrO3)2 Fe(BrO3)3 Co(BrO3)2 Ni(BrO3)2 Cu(BrO3)2 Zn(BrO3)2 Ga Ge As Se Br2O3
    Br2O5
    Kr
    RbBrO3 Sr(BrO3)2 Y(BrO3)3 Zr Nb Mo Tc Ru Rh Pd AgBrO3 Cd In Sn Sb Te I Xe
    Cs Ba(BrO3)2 * Lu(BrO3)3 Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(BrO3)3 Ce(BrO3)3 Pr(BrO3)3 Nd(BrO3)3 Pm(BrO3)3 Sm(BrO3)3 Eu(BrO3)3 Gd(BrO3)3 Tb(BrO3)3 Dy(BrO3)3 Ho(BrO3)3 Er(BrO3)3 Tm(BrO3)3 Yb(BrO3)3
    ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No


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