Ammonium phosphomolybdate
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Other names Ammonium molybdophosphate Triammonium 12-molybdophosphate | |
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ECHA InfoCard | 100.031.545 |
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Properties | |
Chemical formula | (NH4)3PMo12O40 |
Molar mass | 1876.35 g/mol |
Appearance | Yellow crystals |
Melting point | Decomposes |
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Warning | |
Hazard statements | H315, H319, H335[2] |
Precautionary statements | P261, P305+P351+P338[2] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references |
Chemical compound
Ammonium phosphomolybdate is the inorganic salt of phosphomolybdic acid with the chemical formula (NH4)3PMo12O40. The salt contains the phosphomolybdate anion, a well known heteropolymetalate of the Keggin structural class.
Synthesis
Ammonium phosphomolybdate can be made by heating ammonium orthomolybdate combined with phosphoric acid and nitric acid, yielding ammonium nitrate, water, and a yellow precipitate of ammonium phosphomolybdate is obtained.[3]
- 12 (NH4)6Mo7O24(H2O)4 + 7 Na2HPO4(H2O) + 65 HNO3 → 7 (NH4)3Mo12PO40 + 51 NH4NO3 + 14 NaNO3 + 56 H2O
Normally, it often exists as a hexahydrate, a dark yellow fine crystal which is poorly soluble in water.[3]
It is also obtained as a test result for phosphate ions.
References
- ^ ChemicalBook: http://www.chemicalbook.com/ChemicalProductProperty_EN_CB6162083.htm
- ^ a b "Ammonium phosphomolybdate hydrate".
- ^ a b Dias, José Alves; Dias, Sílvia Cláudia Loureiro; Caliman, Ednéia (2014). "Keggin Structure Polyoxometalates". Inorganic Syntheses: Volume 36. Vol. 36. pp. 210–217. doi:10.1002/9781118744994.ch39. ISBN 9781118744994.
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Ammonium salts
monatomic anions |
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oxyanions |
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other anions |
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- Aluminon
- Ammonium acetate
- Ammonium adipate
- Ammonium benzoate
- Ammonium bituminosulfonate
- Ammonium carbamate
- Ammonium citrate
- Ammonium diethyl dithiophosphate
- Ammonium ferric citrate
- Ammonium formate
- Ammonium fumarate
- Ammonium glutamate
- Ammonium lactate
- Ammonium lauryl sulfate
- Ammonium malate
- Ammonium nonanoate
- Ammonium oxalate
- Ammonium picrate
- Ammonium perfluorononanoate
- Ammonium propionate
- Ammonium thioglycolate
- Cupferron
- Ferric ammonium oxalate
- Murexide